The images, simulation, and analysis presented here show the complicated dynamics that occur at the atomic edge of a singlelayer graphene sheet. Thermal dynamics of graphene edges investigated by. This study of an ideal lowdimensional interface, a hole in graphene, exhibits the complex behavior of atoms at a boundary. You are using an old browser, click here to download pdf. Controlled formation of sharp zigzag and armchair edges in. In this report, we present raman spectroscopy investigation of the thermal stability and dynamics of graphene edges. Structural relaxation time and dynamic shear modulus of. Most previous tem studies on graphene edges have relied on electronbeam sputtering onto the. We investigated the mechanism of edge reconstruction and demonstrated the stability of the zigzag edge configuration. Stability and dynamics of vacancy in graphene flakes.
Chabal department of materials science and engineering, the university of texas at dallas, richardson, tx 75080, u. From graphene constrictions to single carbon chains iopscience. The authors results provide solid evidence of magnetism at graphene edges, and show that edge spins have potentially useful quantum dynamics. Molecular dynamics simulation of graphene sinking during. The armchair edge is generally considered to be most stable of these two. Graphene, a single atomic layer of carbon atoms bonded in a hexagonal lattice, is one of few materials that are stable in. It is found that graphene edges both armchair and zigzag are not stable and undergo modifications even at temperature as low as 200 c. Direct electric field imaging of graphene defects nature. Department of materials science and engineering, massachusetts institute of technology, 77 massachusetts avenue, cambridge, massachusetts 029, united states article views are the countercompliant sum of full text article downloads since november 2008 both pdf and html across all institutions. Density functional theory calculations show that graphene flakes with monovacancy at the edge are energetically more stable than the flakes. The sample was prepared as described previously 24, and details of the mi. Diamond and graphite are structures of carbon with a three. Finally, single carbon atom chain bridges between graphene.
The conductivity at the edges of graphene devices is different to that of the central material, researchers have discovered. The team microscope provides realtime atomic resolution, and the electron beam at 80 kev acts as an energy bath that allows the dynamics of edge reconstruction and hole growth to be observed. Pdf although the physics of materials at surfaces and edges has been extensively studied, the movement of individual atoms at an isolated edge has not. High quality cvd graphene of transferred by the clt. The rearrangement of bonds and beaminduced ejection of carbon atoms are recorded as the hole grows. On the basis of polarized raman results, we provide possible structural models on how graphene edges change during annealing. Image showing the differences along the edge of the graphene researchers at the national. Gnr edges using a molecular dynamics md implementation of the lcbopii. The atomic edge configurations are monitored in realtime and the edgeconfigurationdependent dynamics, and stability are analysed using both. The temperature dependence of structural relaxation time and dynamic shear modulus of bulk glassy graphene has been partially determined using coarsegrained molecular dynamics simulations in ref the relaxation process of the graphene melt grows enormously with cooling up to 1 ns.
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